Photoinduced C(sp 3 )–H Amidation with Sulfilimines via Energy‐Transfer Catalysis

Advanced Synthesis & Catalysis 2026

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Authors: Zhe Jin, Xia Liu, Lu Kang, Xinyu Lu, Tingwei Yu, Penghao Jia
DOI: 10.1002/adsc.70280
Cited by: 2
References: 48

Abstract

Visible light‐mediated selective amidation of unactivated C(sp 3 )H bonds is presented with acyl sulfilimines as free nitrene precursors via triplet–triplet energy transfer pathway. Both intermolecular and intramolecular reactions were achieved under mild, additive‐free conditions without metal–nitrenoids formed. This protocol offers a widely applicable approach to access various synthetically versatile compounds, including N ‐acyl hemiaminal ether, benzo[ e ][1,3]oxazin‐4‐one, and isoindolin‐1‐one derivatives in a selective manner.

Fields of Study & Subjects

Radical Photochemical Reactions Catalytic C–H Functionalization Methods Synthesis and Catalytic Reactions

Publication details

Journal / source
Advanced Synthesis & Catalysis
Publisher
Wiley
Volume
368
Issue
3
Publication date
2 February 2026
Language
EN