Electrochemical Migratory Cyclization of N ‐Acylsulfonimide and N ‐Arylsulfonyl Benzothiamide
Abstract
An electrochemical migratory cyclization of N ‐acylsulfonylimine readily generates the biologically interesting sulfonylimine‐functionalized benzothiazine. The implementation of continuous flow electrolysis further enhances reaction efficiency and enables gram‐scale synthesis of this heterocyclic framework, providing the material basis for future biological activity studies. In addition, a straightforward electrochemical entry to the previously inaccessible benzothiazepine from N ‐arylsulfonyl benzothioamide is developed.
Fields of Study & Subjects
Radical Photochemical Reactions
Sulfur-Based Synthesis Techniques
Synthesis and Catalytic Reactions
Publication details
- Journal / source
- Advanced Synthesis & Catalysis
- Publisher
- Wiley
- Volume
- 368
- Issue
- 4
- Publication date
- 15 February 2026
- Language
- EN