Stability of Perovskite Indoor Photovoltaics: A Focused Review and a Call for Standardized Stability Reporting

ABSTRACT Metal halide perovskite indoor photovoltaics (IPVs) are the top contenders in terms of efficiency among emerging IPV technologies. The state‐of‐the‐art perovskite IPVs have already achieved reported efficiencies above 44%, indicating their significant potential. However, only a small percentage of reports discuss stability measurements, with approximately 7% adopting the International Summit on Organic PV Stability (ISOS) protocol for stability evaluation. A standard for the stability assessment of emerging thin film IPVs still lags. This research area remains largely unexplored, yet it is essential to the commercialization of IPV technologies. This review focuses on perovskite‐based IPVs, with an emphasis on device stability. It provides discussions of the origins of degradation in perovskite materials and their corresponding IPV devices. This is followed by an overview of various structure–property–stability strategies, including compositional, interface, and device design engineering for perovskite materials to improve their performance. Finally, the review outlines some existing stability test protocols that could apply to perovskite IPVs, including addressing mitigation issues, such as encapsulation, draws the attention of researchers in the field, and calls for the development of standardized stability test protocols for perovskite IPVs and for understanding how these tests correlate with actual indoor lifespans to enable the commercialization of perovskite IPVs.