β‐Vinylated Tri(1‐adamantyl)phosphine: Synthesis, Characterization, and Application in Gold Catalysis

Chemistry - An Asian Journal 2026 Open access

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Authors: Aituar Tulipkaliyev, Masaya Sawamura, Yusuke Masuda
DOI: 10.1002/asia.70542
Cited by: 0
References: 22

Abstract

A β-vinylated tri(1-adamantyl)phosphine was synthesized from tri(1-adamantyl)phosphine through a photocatalytic cycloaddition/base-induced elimination sequence. The electronic and steric properties of the new phosphine were examined through structural characterization of its chalcogenides and gold complex. The gold complex catalyzed hydroamination of alkynes, demonstrating its potential in transition metal catalysis.

Fields of Study & Subjects

Catalytic Alkyne Reactions Organophosphorus compounds synthesis Organometallic Complex Synthesis and Catalysis

Publication details

Journal / source
Chemistry - An Asian Journal
Volume
21
Issue
1
Pages
e70542–e70542
Publication date
1 January 2026
Language
EN