A Facile Immersion Strategy for Molybdate‐Modified Co/Co(OH) 2 @Cu Nanowires as High‐Efficiency and Durable Electrocatalysts for Alkaline Hydrogen Evolution

Read full text
Authors: Fengye Zhang, Huiping You, Xiyuan Chen, Yue Wang, Xiaojuan Wang, J L Zhang, Enlai Hu, Yating Wan, Zhongwei Chen
Cited by: 1
References: 54

Abstract

ABSTRACT Developing efficient and durable earth‐abundant electrocatalysts for the alkaline hydrogen evolution reaction (HER) is limited by the sluggish water dissociation kinetics. Herein, a facile immersion strategy was proposed to synthesize molybdate species‐modified Co/Co(OH) 2 @Cu (MCC@Cu) nanowires as high‐efficiency alkaline HER electrocatalysts. The introduced molybdate species remarkably promotes the water dissociation process, enhances active site exposure, and improves charge transfer, as revealed by the in situ Raman tests and electrochemical analysis. As a result, the as‐prepared MCC@Cu nanowires have a low overpotential of 37 mV at 10 mA cm −2 , which is much lower than that of the molybdate‐free one (184 mV). This work offers a facile and scalable method for the design of molybdate‐modified electrocatalysts toward alkaline HER.

Fields of Study & Subjects

Electrocatalysts for Energy Conversion Advanced battery technologies research Ammonia Synthesis and Nitrogen Reduction

Publication details

Journal / source
Chemistry - An Asian Journal
Publisher
Wiley
Volume
21
Issue
11
Pages
e70841–e70841
Publication date
1 June 2026
Language
EN