Design Strategy for Sheet‐Type Composite Electrodes in All‐Solid‐State Batteries Operable Under Minimal Stack Pressure Enabled by Cold Isostatic Pressing

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Authors: Teppei Ohno, Yosuke Ugata, Naoaki Yabuuchi
Cited by: 2
References: 44

Abstract

All‐solid‐state batteries (ASSBs) employing sulfide‐based solid electrolytes are attractive energy storage systems because of their potential advantages, such as efficient single‐ion conduction and the absence of electrolyte leakage. Although pellet‐type cells are commonly used in laboratory electrochemical testing under high stack pressure, practical application demands scalable sheet‐type configurations operable under minimal stack pressure. This study demonstrates the feasibility of sheet‐type ASSBs fabricated via slurry casting combined with cold isostatic pressing (CIP) for operation under minimal stack pressure. CIP process allows uniform densification and intimate interparticle contact, resulting in the formation of continuous lithium‐/electron‐conducting pathways within the composite electrode. In addition to the processing pressure, the composite electrode formulation with a dimensionally invariable positive electrode material, Li 8/7 Ti 2/7 V 4/7 O 2 , is systematically optimized by tuning the conductive additive content to balance ionic and electronic conduction pathways, which is a critical factor for maximizing electrochemical performance. Furthermore, the optimized composite electrodes with Li 8/7 Ti 2/7 V 4/7 O 2 show stable long‐term cycling under minimal stack pressure (

Fields of Study & Subjects

Advanced Battery Materials and Technologies Advancements in Battery Materials Advanced battery technologies research

Publication details

Journal / source
ChemElectroChem
Publisher
Wiley
Volume
13
Issue
6
Publication date
10 March 2026
Language
EN