The Palladium(IV)‐Centered Hexatungstate Ion [Pd IV W 6 O 24 ] 8−

Chemistry - A European Journal 2026 Open access

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Authors: Pooja Kulashri, Xiang Ma, Mahmoud Elcheikh Mahmoud, Bassem S. Bassil, Talha Nisar, Veit Wagner, Samer Dawoud, Laurent Ruhlmann, Ulrich Kortz
DOI: 10.1002/chem.71182
Cited by: 1
References: 33

Abstract

ABSTRACT We report on the synthesis of the palladium(IV)‐containing hexatungstate [Pd IV W 6 O 24 ] 8− ( PdW 6 ) with a central 6‐coordinated Pd IV ion, which is surrounded by a ring of six edge‐shared WO 6 octahedra. The sodium salt of PdW 6 was structurally characterized in the solid state by multiple techniques, and the solution redox chemistry was investigated by electrochemistry. The catalytic hydrogenation of o ‐xylene using supported PdW 6 as a precatalyst was also studied.

Fields of Study & Subjects

Thermal Expansion and Ionic Conductivity Polyoxometalates: Synthesis and Applications Inorganic Chemistry and Materials

Publication details

Journal / source
Chemistry - A European Journal
Publisher
Wiley
Volume
32
Issue
35
Pages
e71182–e71182
Publication date
1 June 2026
Language
EN