Tracking the Reaction of Organoazides with Linear Chromium Silylamides

European Journal of Inorganic Chemistry 2026 Open access

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Authors: Andres Gonzalez, Sophie Schäfer, Ting-Yi Chen, Serhiy Demeshko, Franc Meyer, C. Gunnar Werncke
DOI: 10.1002/ejic.70226
Cited by: 1
References: 68

Abstract

The reaction of organoazides with a linear chromium(I) silylamide leads to the observation of rare monomeric and dimeric imido chromium complexes, as well as labile azide adducts. Further, the first trigonal chromium oxide complex is reported, obtained from the reaction of a linear chromium(II) silylamide with either acylazide or Me 3 NO.

Fields of Study & Subjects

Organometallic Complex Synthesis and Catalysis Chemical Reactions and Mechanisms Oxidative Organic Chemistry Reactions

Publication details

Journal / source
European Journal of Inorganic Chemistry
Publisher
Wiley
Volume
29
Issue
18
Publication date
15 May 2026
Language
EN