Water cluster triggered vitrification in HKUST ‐1 MOF crystal under pressure

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Authors: Jianguo Sun, Chin Ho Kirk, Yunchuan Pu, Athulya S. Palakkal, Lewis Kien Juen Ting, Fei Wang, Kok Chan Chong, Tuo Wang, Saad Aldin Mohamed, Bin Liu, Jianwen Jiang, Anthony K. Cheetham
+2 more Dan Zhao, John Wang
Cited by: 3
References: 52

Abstract

Abstract Metal–organic framework (MOF) glasses feature several unique dynamic and thermodynamic properties that differentiate them from their crystalline counterparts. However, the formation of MOF glasses usually requires the melt‐quenching of molten MOFs from relatively high temperatures. In practice, this approach is quite limited because most MOFs decompose below their melting points. Herein, we demonstrate a direct crystal‐to‐glass transition in HKUST‐1 MOF that has been achieved at room temperature and a relatively low pressure of

Fields of Study & Subjects

Metal-Organic Frameworks: Synthesis and Applications Glass properties and applications Magnesium Oxide Properties and Applications

Publication details

Journal / source
InfoMat
Publisher
Wiley
Volume
8
Issue
3
Publication date
15 January 2026
Language
EN