QCD scattering amplitudes and prescriptive unitarity

A bstract We present a systematic framework for the maximally-transcendental part of planar QCD scattering amplitudes and perform the first bootstrap computation of six-gluon MHV amplitudes in massless QCD at the symbol level. By analyzing the maximal weight projection of amplitudes at the integrand level, we relate their maximally-transcendental parts to prescriptive unitarity integrals. This reveals a novel analytic structure: the prefactors multiplying the functions of maximal transcendentality are identified with the four-dimensional leading singularities of the theory. As a consequence, these prefactors admit a complete classification and can be computed using on-shell diagrams , a formalism originally developed in $$ \mathcal{N} $$ N =4 super Yang-Mills theory. As a concrete application, we determine the two-loop prefactors for planar MHV gluon amplitudes at arbitrary multiplicity. Combining these prefactors with recent advances in the planar two-loop six-point function space and explicit six-point prescriptive-unitarity input, we construct a complete symbol ansatz and uniquely fix the maximally-transcendental part of the two-loop six-gluon MHV QCD amplitudes by imposing physical constraints. The resulting symbols are expressible in a reduced 137-letter alphabet, suggesting that this alphabet is complete for two-loop six-point massless MHV scattering. We also discuss the implications for multi-collinear splitting and multi-soft functions.