Transient regimes in conservatively perturbed equilibria: New kinetic invariances
Abstract
New developments of kinetic behavior of chemical systems with conservatively perturbed equilibria are presented, specifically for the linear cases with one degree of freedom. New analytical expressions for transition curves with over- and under-equilibria, or "master curves" have been obtained. For two-step linear reactions, these expressions generate new kinetic invariances which are simple functions of kinetic coefficients. The found expressions will be useful for identifying the underlying mechanism, specifically with applications to solving the inverse problem in chemical kinetics.
Fields of Study & Subjects
Control Systems and Identification
Thermal and Kinetic Analysis
Advanced Physical and Chemical Molecular Interactions
Publication details
- Journal / source
- Chemical Engineering Journal
- Volume
- 531
- Pages
- 174230–174230
- Publication date
- 16 February 2026
- Language
- EN