Calibration-Free Analysis of Li Isotope Ratios Using Laser Ablation and Laser Absorption Spectroscopy

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Authors: Mark C. Phillips, Kyle A. Makovsky, Richard E. Stevens, Elizabeth J. Kautz, S. S. Harilal
Cited by: 1
References: 48

Abstract

Li ratios demonstrates relative isotopic precisions of 0.6-1.8% for spectra acquired in 30 s. Isotope ratios determined from the spectral fits show relative accuracy within -0.3% to -5% of ICP-MS measurements, without requiring calibration to external standards, and offering a rapid analysis approach to lithium isotope determination in solid materials relevant to nuclear energy, safeguards, and geochemistry.

Fields of Study & Subjects

Analytical chemistry methods development Laser-induced spectroscopy and plasma Atomic and Subatomic Physics Research

Publication details

Journal / source
Analytical Chemistry
Publisher
American Chemical Society (ACS)
Volume
98
Issue
25
Pages
18873–18881
Publication date
19 June 2026
Language
EN