Mn-Doped NiCoP Electrolysts for Highly Efficient Alkaline Water Electrolysis

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Authors: Xinlan Guo, Xinrui Bai, Xia Yu, Young-Rae Cho, Xiang Wu
Cited by: 5
References: 52

Abstract

Efficient overall water splitting urgently requires electrocatalysts that concurrently drive both the hydrogen evolution reaction (HER) and the oxygen evolution reaction (OER). Thereinto, NiCoP catalyst emerges as a promising candidate. Its distinctive electronic structure and tailored microstructure enable efficient interfacial electron transfer, thereby enhancing the overall catalytic performances. Although it possesses high activity for the HER, it remains comparatively poor for the OER performance. This dilemma limits its overall efficiency in water-splitting applications. In this work, we prepare Mn–NiCoP nanowire arrays on nickel foams (NF). This electrode requires only 75 mV for HER at 10 mA cm –2 . The overall water-splitting cell provided a voltage of 1.63 V at 50 mA cm –2 . It can work stably at 50 mA cm –2 for 150 h in 1 M KOH + seawater.

Fields of Study & Subjects

Electrocatalysts for Energy Conversion Ammonia Synthesis and Nitrogen Reduction Advanced battery technologies research

Publication details

Journal / source
Energy & Fuels
Publisher
American Chemical Society (ACS)
Volume
40
Issue
12
Pages
6341–6348
Publication date
16 March 2026
Language
EN