Silane Redistribution Catalyzed by [Mes-B-TMP] + Borinium Ion
Abstract
plays a pivotal role in modulating the Lewis acidity of the boron center, enabling reversible Si-H activation while preventing irreversible B-C bond cleavage and catalyst decomposition. These findings highlight the potential of electronically tuned borinium ions as catalysts for activating inert substrates in organic transformations.
Fields of Study & Subjects
Organoboron and organosilicon chemistry
Catalytic Cross-Coupling Reactions
Catalytic C–H Functionalization Methods
Publication details
- Journal / source
- Inorganic Chemistry
- Publisher
- American Chemical Society (ACS)
- Volume
- 65
- Issue
- 4
- Pages
- 2117–2121
- Publication date
- 21 January 2026
- Language
- EN