Thermodynamic and Molecular Analysis of Polar Adsorption Enthalpy: Modeling of Lewis Acid–Base Energetics at Solid Surfaces
Abstract
) terms was found essential to reproduce experimental linearity and capture the physical duality of real surfaces. The new model thus transforms adsorption thermodynamics from an empirical linear model into a physically interpretable, statistically validated law. This formulation provides a unified energetic basis for describing the amphoteric and polarizable nature of oxides, polymers, and hybrid materials, and offers a predictive platform for future studies on temperature-dependent adsorption and electronic structure-surface energy correlations.
Fields of Study & Subjects
Adsorption
diffusion
and thermodynamic properties of materials
Chemical Thermodynamics and Molecular Structure
Adsorption and biosorption for pollutant removal
Publication details
- Journal / source
- Langmuir
- Publisher
- American Chemical Society (ACS)
- Volume
- 42
- Issue
- 4
- Pages
- 3539–3561
- Publication date
- 20 January 2026
- Language
- EN