Competing Effects of Network Architecture and Composition on Polydomain Liquid Crystal Elastomers

High Resolution Image Download MS PowerPoint Slide Main-chain liquid crystal elastomers (LCEs) are synthesized to investigate the interplay of the composition and network structure on LCE nematic-to-isotropic (N–I) transitions. We focus on networks synthesized from liquid crystalline oligomers reacted with tri- or tetrafunctional nonmesogenic cross-linker molecules. We find that coupling between mesogens and the polymer backbone increases with the degree of cross-linking. However, this enhanced coupling competes with mesogenic dilution arising from the cross-linker molecules to determine the N–I transition temperature ( T NI ). When cross-linker molecules are dilute, the degree of cross-linking directly correlates to the change in T NI from the oligomer to LCE (Δ T NI ) through mesogen–backbone coupling. In this regime, Δ T NI ranges from 2.9 to 12.2 °C and 2.9–13.9 °C for tri- and tetrafunctional cross-linkers, respectively. At high cross-linker concentrations, deviations from this linear relationship appear. Further, the fractional mesogen content within an oligomer chain induces molecular weight-dependent mesogenic dilution effects arising from the flexible spacer molecules. Analysis of the N–I transition peak reveals a maximum latent heat per gram of mesogen (Δ H NI,mes ) for this system.