Photoredox-Enabled and Thianthrenation-Promoted Access to Arene Sulfinamides En Route to Other S(VI) Compounds

Organic Letters 2026

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Authors: Manveer Patel, Soumik Mondal, Subhadeep Hazra, Sandipan Mondal, Dharmendra Kumar Tiwari, Vinod P. Singh, Jaideep Saha
DOI: 10.1021/acs.orglett.5c04745
Cited by: 2
References: 48

Abstract

Sulfinylation of organic compounds to sulfinamides is an attractive means to access various important sulfur(VI) compounds through follow-up oxidative reactions. Herein, we report a photoredox-enabled arene sulfinaylation, processing through aryl thianthrenium (Ar-TT + ) salts. High regio- and chemoselectivities of arene thianthrenation leverage structural diversity into the corresponding sulfinamides. Follow-up reactions and mechanistic investigations were performed in the study.

Fields of Study & Subjects

Sulfur-Based Synthesis Techniques Click Chemistry and Applications Catalytic C–H Functionalization Methods

Publication details

Journal / source
Organic Letters
Publisher
American Chemical Society (ACS)
Volume
28
Issue
2
Pages
669–674
Publication date
1 January 2026
Language
EN