Paired Electrolysis-Promoted Ni-Catalyzed Decarboxylative Cross-Couplings of Potassium Malonate Monoesters with Aryl Bromides
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We report a paired electrolysis-promoted Ni-catalyzed decarboxylative cross-coupling of aryl bromides with potassium malonate monoesters. Carried out in an undivided electrolytic cell under mild reaction conditions, this strategy exhibits broad compatibility with a wide range of aryl/heteroaryl and vinyl bromides, offering a practical and efficient protocol for the synthesis of α-aryl esters.
Fields of Study & Subjects
Catalytic Cross-Coupling Reactions
Radical Photochemical Reactions
Catalytic C–H Functionalization Methods
Publication details
- Journal / source
- Organic Letters
- Volume
- 28
- Issue
- 12
- Pages
- 3913–3917
- Publication date
- 16 March 2026
- Language
- EN