Three-Component Carbosulfonylation of Alkenes via Single-Atom Nickel Photocatalysis

Organic Letters 2026

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Authors: Hao Wang, Mingyao Wu, Qian Yang, Wentao Wang, Yurong Tang, Yunfei Cai
DOI: 10.1021/acs.orglett.6c00998
Cited by: 3
References: 40

Abstract

A heterogeneous metallaphotocatalytic carbosulfonylation of vinyl amides has been developed using a recyclable bifunctional poly(heptazine imide) (PHI) photocatalyst bearing single-atom Ni sites (bpyNi SA -PHI). This robust protocol enables efficient and sustainable access to diverse vicinal aminosulfones at exceptionally low catalyst loadings (0.43–0.86 mol %) under mild conditions.

Fields of Study & Subjects

Sulfur-Based Synthesis Techniques Radical Photochemical Reactions Catalytic C–H Functionalization Methods

Publication details

Journal / source
Organic Letters
Publisher
American Chemical Society (ACS)
Volume
28
Issue
13
Pages
4331–4336
Publication date
23 March 2026
Language
EN