Three-Dimensional Functionalization of Macrocycles: Porphyrin and Polycyclic Carbon Cage Hybrid

Organic Letters 2026 Open access

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Authors: Katarzyna Stasiak, Katarzyna A. Ślepokura, Aleksandra Szumańska, Michał J. Białek, Lechosław Latos‐Grażyński, Anna Berlicka
DOI: 10.1021/acs.orglett.6c01942
Cited by: 1
References: 26

Abstract

A three-dimensional functionalization strategy for porphyrins affords a hybrid architecture integrating a porphyrinic structural motif with a rigid, chiral bisnorditwistane cage. The resulting system combines a sterically demanding carbon framework with a planar triheterocyclic fragment. The macrocycle exhibits a well-defined two-step protonation behavior.

Fields of Study & Subjects

Supramolecular Chemistry and Complexes Synthesis and Properties of Aromatic Compounds Molecular Sensors and Ion Detection

Publication details

Journal / source
Organic Letters
Publisher
American Chemical Society (ACS)
Volume
28
Issue
24
Pages
7747–7752
Publication date
8 June 2026
Language
EN