Heteroatom-Induced Defect Growth for Zeolites Beta with Hierarchical Pores for Heavy Oil Cracking

ACS Applied Nano Materials 2026

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Authors: Chun Ming Zheng, Zhaojun Liu, Chenyang Zhao, Jinwei Wang, Yanlei Sha, H.J. Liu, H.J. Liu, Hong Meng, Xinye Fan, Gen Li, Hongtao Liu, Hongtao Liu
DOI: 10.1021/acsanm.5c04508
Cited by: 1
References: 44

Abstract

Hierarchical zeolites Beta have been demonstrated to be advantageous in the catalytic conversion of large molecules due to the elimination of transport limitation. However, obtaining zeolite Beta directly with hierarchical pores in one step is still a great challenge. Herein, we report a simple one-step process to obtain hierarchical zeolite Beta by a defect growth method induced by the grafting of Ca atoms. This strategy is feasible in the formation of unstable Si–O–Ca bonds in comparison with Si–O–Al. Meanwhile, subsequent calcination will lead to breaking of the unstable Ca–O bonds. As a direct result, mesopores will be generated in this totally inorganic synthesis system. This defect-engineering mesopore generation strategy established an avenue for sustainable zeolite design with an eco-friendly procedure.

Fields of Study & Subjects

Zeolite Catalysis and Synthesis Mesoporous Materials and Catalysis Catalysis and Hydrodesulfurization Studies

Publication details

Journal / source
ACS Applied Nano Materials
Publisher
American Chemical Society (ACS)
Volume
9
Issue
2
Pages
983–991
Publication date
6 January 2026
Language
EN