Electrolyte-Controlled Oxygen Reduction Reaction Via High-Performance Nanoconfined Pt–N 4 –C 8 Assay
Abstract
The atomically dispersed Pt–N 4 –C 8 –X with metal loaded (0 to 10 wt %) and the H 2 SO 4 concentration from 5 to 10 M tunes the structure and intermediate adsorption energetics (*O 2, *OOH, *OH, and *O), demonstrating superior acidic ORR activity. Pt–N 4 –C 8 –SOOH achieved 36 ± 8 mV and 173 ± 10 mV overpotentials at 10 and 100 mA cm –2, respectively, for 5 M H 2 SO 4, 5 wt % metal loading, exhibiting j 0 ≈ 2.05 mA cm –2, Tafel slope (≈72 mV dec –1 ), 112.8 Ag 1– mass activity, and up to 3.1-fold TOF enhancements. Chronoamperometry confirms sustained activity for >200 h with minimal overpotential increase (Δη ≈ 12–18 mV) at 10–100 mA cm –2, while maintaining reproducibility across batches.
Fields of Study & Subjects
Electrocatalysts for Energy Conversion
CO2 Reduction Techniques and Catalysts
Catalytic Processes in Materials Science
Publication details
- Journal / source
- ACS Applied Nano Materials
- Volume
- 9
- Issue
- 6
- Pages
- 2693–2701
- Publication date
- 4 February 2026
- Language
- EN