Metal–Hydrogen Batteries and Decoupled Electrolyzers: Converging Pathways for Hydrogen-Integrated Energy Storage

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Authors: Laura Sanchez-Cupido, Begoña Acebedo, Nagore Ortiz-Vitoriano, Paramaconi Rodríguez
Cited by: 4
References: 50

Abstract

High Resolution Image Download MS PowerPoint Slide Electrochemical energy storage and hydrogen conversion have historically been developed as separate technologies, yet their chemistries and engineering challenges overlap profoundly. Metal–hydrogen (M–H 2 ) batteries and redox-mediated, membrane-free electrolyzers both rely on reversible hydrogen redox chemistry in aqueous or hybrid electrolytes. This Perspective examines how these systems, once considered distinct, are converging at the level of redox chemistry, materials challenges, and benchmarking needs while retaining distinct architectures and engineering constraints for dispatchable, long-duration energy storage. It summarizes benchmark metrics for each platform, identifies shared scientific foundations, and outlines design principles for mediators, electrodes, and interfaces. Emphasis is placed on best practices for standardized testing and reporting, cross-disciplinary benchmarking, and near-term research directions. By viewing M–H 2 batteries and decoupled electrolyzers as complementary elements rather than competitors, it becomes possible to envision a cohesive hydrogen-integrated energy infrastructure spanning seconds-to-seasons storage.

Fields of Study & Subjects

Advanced battery technologies research Electrocatalysts for Energy Conversion Advanced Battery Materials and Technologies

Publication details

Journal / source
ACS Energy Letters
Publisher
American Chemical Society (ACS)
Volume
11
Issue
4
Pages
3014–3023
Publication date
27 March 2026
Language
EN