An Mg Solid Solution Affords a Less Toxic and More Stable ZIF-8

ACS Omega 2026 Open access

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Authors: Nicola di Nicola, Enrico Spoletti, Pierre Cezade, Andrea Lazzarini, Matteo Lusi
DOI: 10.1021/acsomega.5c13152
Cited by: 1
References: 48

Abstract

affords a mixed-metal ZIF-8 analogue with up to 20% of the alkali heart. Besides reducing the dose of zinc, the solid solution shows increased water stability under mildly acidic conditions. DFT calculations point to a reduction of the MOF's polarizability as a cause for the observed behavior. Ideally, the changes in the Zn/Mg ratio would correspond to a modulation of such stability; however, equal stability improvement was measured over a range of compositions.

Fields of Study & Subjects

Metal-Organic Frameworks: Synthesis and Applications Magnesium Oxide Properties and Applications Parathyroid Disorders and Treatments

Publication details

Journal / source
ACS Omega
Publisher
American Chemical Society (ACS)
Volume
11
Issue
18
Pages
26629–26634
Publication date
28 April 2026
Language
EN