Distance-Dependent, Rate-Accelerating and Diastereoselective Directing Effects in Decatungstate-Mediated Stereoediting Reactions
Abstract
-configured starting materials. The discovery that noncovalent interactions can be used to guide the reactivity of excited-state DT fundamentally transforms our understanding of this reagent's control paradigms, opening the door to the design of new strategies to tune the selectivity of DT-mediated HAT steps.
Fields of Study & Subjects
Radical Photochemical Reactions
Synthetic Organic Chemistry Methods
Chemical Reactions and Isotopes
Publication details
- Journal / source
- Journal of the American Chemical Society
- Publisher
- American Chemical Society (ACS)
- Volume
- 148
- Issue
- 17
- Pages
- 17728–17735
- Publication date
- 21 April 2026
- Language
- EN