Chemical Control of Supramolecular Copolymerization by Modulating the Chirality Transfer of Helical-Chiral Pillar[5]arenes

Journal of the American Chemical Society 2026

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Authors: De‐Hui Tuo, Kazuma Yasuhara, Yuuya Nagata, Moe Ogasawara, Hitoshi Asakawa, Shunsuke Ohtani, Kenichi Kato, Tomoki Ogoshi
DOI: 10.1021/jacs.5c23106
Cited by: 4
References: 72

Abstract

-helical basic and acidic P5A monomers. The polymerization can be accelerated by acidic or basic additives and suppressed by the addition of guest molecules. Because of the multiple helical-sense-matched ion-pairing interactions, the resulting supramolecular copolymer exhibited exceptional stability in polar solvents, at high temperatures, and in harsh environments.

Fields of Study & Subjects

Synthesis and Properties of Aromatic Compounds Supramolecular Chemistry and Complexes Supramolecular Self-Assembly in Materials

Publication details

Journal / source
Journal of the American Chemical Society
Publisher
American Chemical Society (ACS)
Volume
148
Issue
15
Pages
15939–15948
Publication date
8 April 2026
Language
EN