Hydrogen Spillover from Pt, Pd, and Au Evaluated with MnO x Temperature-Programmed Reduction

Abstract Hydrogen spillover occurs when H2 adsorbs on an active metal and is then transferred to a reducible metal oxide. While spillover is involved in many catalytic reactions, fundamental studies of spillover have been limited by the paucity of experimental methods available to study it. Here, we develop an experimental temperature-programmed reduction (TPR) protocol to rapidly compare spillover from different metals (Pt, Pd, Au ) onto P25 titania, using MnOx reduction probe reaction. X-ray photoelectron and UV–visible spectroscopies indicated reduction to MnO in the presence and absence of active metals, and quantitative H2 consumption measurements were consistent across all samples. Observed MnOx reduction temperatures, which decrease by shifting as much as 150 °C, depend strongly on the metal loading and confirm H2 activation occurs at metal sites. Adding only 300 ppm Au caused the Kissinger apparent activation energy to decrease from 55 to