Theoretical investigation of dioxygen activation and hydrocarbon oxidation catalysed by bioinspired metal–organic frameworks

Chemical Communications 2026

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Authors: Zi-Xian Zhan, Bowen Shi, Shoujun Wang, Yufen Zhao, Dongru Sun, Yong Wang
DOI: 10.1039/d5cc05802c
Cited by: 0
References: 37

Abstract

Dioxygen activation by a biomimetic FeZn 4 (prv) 4 (btdd) 3 MOF to form high-spin ( S = 2) iron( iv )–oxo active species was revealed to proceed via two-state reactivity.

Fields of Study & Subjects

Metal-Catalyzed Oxygenation Mechanisms Metal-Organic Frameworks: Synthesis and Applications Magnetism in coordination complexes

Publication details

Journal / source
Chemical Communications
Volume
62
Issue
10
Pages
3287–3290
Publication date
1 January 2026
Language
EN