Defective TiO x spontaneously triggers the hydrogenation activity of silver

Chemical Communications 2026 Open access

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Authors: Duan Xinping, Wei Zhao, Zuo‐Chang Chen, Jianwei Zheng, Haiqiang Lin, Linmin Ye, Youzhu Yuan
DOI: 10.1039/d5cc06528c
Cited by: 1
References: 32

Abstract

The reactive metal–support interaction (RMSI) between Ag and defective TiO x spontaneously triggers the selective silver-catalyzed hydrogenation of dimethyl oxalate to methyl glycolate, enabling a >5-fold increase in TOF without prereduction.

Fields of Study & Subjects

Catalysis for Biomass Conversion Nanomaterials for catalytic reactions Environmental remediation with nanomaterials

Publication details

Journal / source
Chemical Communications
Publisher
Royal Society of Chemistry (RSC)
Volume
62
Issue
10
Pages
3291–3295
Publication date
1 January 2026
Language
EN