Efficient singlet oxygen ( 1 O 2 )-mediated photocatalysis-driven Achmatowicz rearrangement based on a gas–liquid–solid tri-phase system
Abstract
)-mediated Achmatowicz rearrangement. Compared with conventional diphase systems, the triphase interface enables a distinct reaction pathway, achieving a 4-fold higher formation rate and improved best selectivity from 39.3% to 61.1%. The enhanced performance is attributed to high interfacial oxygen availability and the improved utilization of photogenerated carriers.
Fields of Study & Subjects
TiO2 Photocatalysis and Solar Cells
Innovative Microfluidic and Catalytic Techniques Innovation
Fluid Dynamics and Thin Films
Publication details
- Journal / source
- Chemical Communications
- Publisher
- Royal Society of Chemistry (RSC)
- Volume
- 62
- Issue
- 12
- Pages
- 3893–3896
- Publication date
- 1 January 2026
- Language
- EN