Design, synthesis and reactivity of N -adamantyl cyclometalated cyclic(alkyl)(amino)carbene ruthenium complexes in Z -selective olefin metathesis

Chemical Communications 2026 Open access

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Authors: Clément Casalta, Fanny Morvan, Sophie Colombel‐Rouen, Thierry Roisnel, Rodolphe Jazzar, Angelino Doppiu, Marc Mauduit
DOI: 10.1039/d5cc06689a
Cited by: 2
References: 39

Abstract

A new Z -selective cyclometalated cyclic(amino)(alkyl)carbene Ru-complex was synthesized. It demonstrated high Z -selectivity in various self- and cross-metathesis reactions.

Fields of Study & Subjects

Synthetic Organic Chemistry Methods Cyclopropane Reaction Mechanisms N-Heterocyclic Carbenes in Organic and Inorganic Chemistry

Publication details

Journal / source
Chemical Communications
Publisher
Royal Society of Chemistry (RSC)
Volume
62
Issue
13
Pages
4099–4102
Publication date
1 January 2026
Language
EN