Reactivity of ketenyl anions towards ammonia

Chemical Communications 2026 Open access

Read full text
Authors: Prakash Duari, Mike Jörges, Sunita Mondal, Kai‐Stephan Feichtner, Viktoria H. Gessner
DOI: 10.1039/d5cc06975k
Cited by: 0
References: 42

Abstract

Alkali metal ketenyls with strong electron-withdrawing groups react with ammonia to form β-ketoamides, or activate all N–H bonds to give trianionic triamides that form dimers with a unique planar triangular {K 6 } 6+ array.

Fields of Study & Subjects

Coordination Chemistry and Organometallics Synthesis and characterization of novel inorganic/organometallic compounds Inorganic and Organometallic Chemistry

Publication details

Journal / source
Chemical Communications
Volume
62
Issue
14
Pages
4293–4297
Publication date
1 January 2026
Language
EN