Crystallographic determination of Lu@ C 2v (9)-C 82 : electronic configuration and encapsulation energy-driven formation preference

Chemical Communications 2026

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Authors: Rui Zhang, Pengwei Yu, Mengyang Li, Xiaoxue Tan, Zhicong Hu, Wangqiang Shen, Lipiao Bao, Xing Lu
DOI: 10.1039/d5cc07103h
Cited by: 0
References: 34

Abstract

Lu@C 82 is captured and demonstrated as Lu 2+ @[ C 2v (9)-C 82 ] 3− , resolving the long-standing valence paradox. Encapsulation energy rationalizes the formation preference.

Fields of Study & Subjects

Fullerene Chemistry and Applications Diamond and Carbon-based Materials Research Carbon Nanotubes in Composites

Publication details

Journal / source
Chemical Communications
Volume
62
Issue
9
Pages
2991–2994
Publication date
1 January 2026
Language
EN