Synthesis and reactivity of a strongly pyramidalized P( iii )-compound embedded into a pyrrolide (ONO) 3− pincer ligand

Chemical Communications 2026 Open access

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Authors: Malte Kaste, Tobias Heilmann, Johannes Kircher, Christopher Golz, Ricardo A. Mata, Manuel Alcarazo
DOI: 10.1039/d5cc07240a
Cited by: 2
References: 39

Abstract

oxidative addition of their respective O-H and N-H bonds at the P-center, delivering the corresponding P(V) species. DFT calculations, as well as kinetic and isotope labelling analyses suggest the assistance of one of the phenolate side arms in the process.

Fields of Study & Subjects

Organometallic Complex Synthesis and Catalysis Synthesis and characterization of novel inorganic/organometallic compounds Synthetic Organic Chemistry Methods

Publication details

Journal / source
Chemical Communications
Publisher
Royal Society of Chemistry (RSC)
Volume
62
Issue
20
Pages
5696–5700
Publication date
1 January 2026
Language
EN