Photoinduced transformations of oxime derivatives via electron donor–acceptor complex activation

Chemical Communications 2026

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Authors: Qianqian Xu, Zong-Bo Xie, Zhang-Gao Le, Zhi-Qiang Zhu
DOI: 10.1039/d5cc07251d
Cited by: 2
References: 90

Abstract

ring-opening of cyclic iminyl radicals, a pathway that converts iminyl radicals into synthetically versatile cyanoalkyl radicals; and (4) formal 1,3- or 1,5-hydrogen atom transfer (HAT) of iminyl radicals for remote C-H functionalization. For each category, we present mechanistic discussions underpinned by spectroscopic, kinetic, and computational evidence, highlight strategic advantages and illustrate the broad synthetic utility of this rapidly evolving platform.

Fields of Study & Subjects

Radical Photochemical Reactions Catalytic C–H Functionalization Methods Sulfur-Based Synthesis Techniques

Publication details

Journal / source
Chemical Communications
Publisher
Royal Society of Chemistry (RSC)
Volume
62
Issue
20
Pages
5575–5587
Publication date
1 January 2026
Language
EN