A dynamic pcu MOF(Zn) containing a ditopic T-shaped [2]rotaxane linker

CrystEngComm 2026 Open access

Read full text
Authors: Hazem Amarne, Alexander Joseph Stirk, Christopher A. O’Keefe, Robert W. Schurko, Stephen J. Loeb
DOI: 10.1039/d5ce01108f
Cited by: 1
References: 41

Abstract

A T-shaped [2]rotaxane linker was used to make a pcu MOF, designated UWDM-16 . SCXRD showed the rotaxanes occupy pores in the material and 2 H SSNMR verified that the macrocyclic wheel is mobile in the solid-state.

Fields of Study & Subjects

Supramolecular Chemistry and Complexes Metal-Organic Frameworks: Synthesis and Applications Supramolecular Self-Assembly in Materials

Publication details

Journal / source
CrystEngComm
Publisher
Royal Society of Chemistry (RSC)
Volume
28
Issue
3
Pages
631–634
Publication date
1 January 2026
Language
EN