Conformational studies of 1,2-di- tert -butoxyethane with special attention to the gauche oxygen effect

Physical Chemistry Chemical Physics 2026 Open access

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Authors: Hidemine Furuya, Takahiro Takekiyo, Ryoichi Wada, Kunihiro Kasezawa, Akihiro Abe, Minoru Kato
DOI: 10.1039/d5cp04244e
Cited by: 0
References: 36

Abstract

The gauche oxygen effect of 1,2-di- tert -butoxyethane was examined. While the tgg ′ conformation was almost entirely suppressed in the presence of bulky terminal groups, the gauche preference characteristic of the glycol unit remains nearly unaffected.

Fields of Study & Subjects

Molecular Spectroscopy and Structure Advanced Physical and Chemical Molecular Interactions Advanced Chemical Physics Studies

Publication details

Journal / source
Physical Chemistry Chemical Physics
Volume
28
Issue
11
Pages
7118–7126
Publication date
1 January 2026
Language
EN