Exploring the cyclization reaction channel for the gas-phase elementary reaction between the silicon nitride radical (SiN, X 2 Σ + ) and isoprene (C 5 H 8 , X 1 A′) to prepare methylazasilacyclohexadienylidenes (SiNC 5 H 7 , X 1 A′)
Abstract
), with the methyl group in isoprene classified as a spectator, thus advancing our fundamental understanding of the organosilicon chemistry through the delivery of synthetic pathways to a distinct class of silicon-containing heterocyclic molecules: methylazasilacyclo-hexadienylidenes.
Fields of Study & Subjects
Synthesis and characterization of novel inorganic/organometallic compounds
Chemical Reactions and Mechanisms
Advanced Chemical Physics Studies
Publication details
- Journal / source
- Physical Chemistry Chemical Physics
- Volume
- 28
- Issue
- 7
- Pages
- 4862–4871
- Publication date
- 1 January 2026
- Language
- EN