Astrochemistry prefers the biomolecule: isomer-selective production of ethanolamine (HOCH 2 CH 2 NH 2 ) in interstellar model ices

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Authors: Joshua H. Marks, Anatoliy A. Nikolayev, Jia Wang, Ivan O. Antonov, Alexander Moiseevich Mebel, Ralf I. Kaiser
Cited by: 0
References: 73

Abstract

NO isomers are selective for ethanolamine while its isomers are not detected. Computations provide support that polar solvation destabilizes nitrogen- and oxygen-centered radicals while lowering the barrier to intramolecular hydrogen transfer, resulting in the selective stabilization and formation of carbon-centered radicals. These findings explain the unexpected abundance of ethanolamine in the interstellar medium, and the apparent isomer-selectivity of this reaction may represent a mechanism by which ice-phase astrochemical reactions are preferential toward the building blocks of life.

Fields of Study & Subjects

Astrophysics and Star Formation Studies Origins and Evolution of Life Space Science and Extraterrestrial Life

Publication details

Journal / source
Physical Chemistry Chemical Physics
Volume
28
Issue
8
Pages
5516–5526
Publication date
1 January 2026
Language
EN