Mechanistic divergence in Rh( iii )-catalyzed cascades: how substrate identity switches between cyclization and migratory insertion

Catalysis Science & Technology 2026

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Authors: Yuanjun Song, Ran Fang, Simeng Qi, Liyuan Meng, Lizi Yang
DOI: 10.1039/d5cy01355k
Cited by: 1
References: 76

Abstract

Density functional theory (DFT) calculations provide a detailed mechanistic understanding of Rh( iii )-catalyzed cyclization reactions involving 8-methylquinoline or 2-methylquinoline- N -oxide and 2-alkynylaniline.

Fields of Study & Subjects

Catalytic C–H Functionalization Methods Catalytic Alkyne Reactions Catalytic Cross-Coupling Reactions

Publication details

Journal / source
Catalysis Science & Technology
Publisher
Royal Society of Chemistry (RSC)
Volume
16
Issue
3
Pages
914–924
Publication date
1 January 2026
Language
EN