Pendant-cation assisted spontaneous axial halide substitution in group 7 M(L)(CO) 3 X complexes

Dalton Transactions 2026 Open access

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Authors: Wesley W. Kramer, Thomas R. Sheridan, Jorge Pérez-Vázquez, Christophe A. Boivin, Amanda M. Browne, Catherine G. Logan, Brian Sanders
DOI: 10.1039/d5dt02433a
Cited by: 1
References: 47

Abstract

The presence of pendant cationic functional groups in group 7 fac -tricarbonyl complexes produces unusual axial-halide substitution reactivity. The effects of the metal, axial halide, and solvent on the ligand substitution equilibrium are presented.

Fields of Study & Subjects

CO2 Reduction Techniques and Catalysts Carbon dioxide utilization in catalysis Ionic liquids properties and applications

Publication details

Journal / source
Dalton Transactions
Publisher
Royal Society of Chemistry (RSC)
Volume
55
Issue
13
Pages
5197–5209
Publication date
1 January 2026
Language
EN