An iron( iv )–oxo intermediate on a carbanionic ligand framework: reactivity and decay pathways

Dalton Transactions 2026

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Authors: Arghyadip Bhowmik, Shreetama Bhattacharya, Sridhar Banerjee, Satadal Paul, Tapan Kanti Paine
DOI: 10.1039/d5dt02524a
Cited by: 0
References: 44

Abstract

the formation of an oxo-bridged dinuclear iron(III) species outperforms productive substrate oxidation. Intermediate 2 represents the unique example of an organoimetallic iron(IV)-oxo intermediate in an unconventional, highly electron-rich carbanionic ligand framework.

Fields of Study & Subjects

Metal-Catalyzed Oxygenation Mechanisms Magnetism in coordination complexes Metal complexes synthesis and properties

Publication details

Journal / source
Dalton Transactions
Volume
55
Issue
7
Pages
3037–3042
Publication date
1 January 2026
Language
EN