Magneto-structural correlations in cobalt( ii )-phenanthroline compounds with chloranilic acid
Abstract
-values for cobalt ions at low temperatures. ESR linewidth analysis, supported by DFT calculations, revealed negligible intermolecular interactions. Static magnetic properties were studied using the temperature and field dependence of magnetization. Comprehensive magnetic modeling of the experimental data provides deeper insight into the subtle influence of different crystal packing arising from solvent exchange on the magnetic properties of the complexes. Additionally, AC magnetic susceptibility studies at low temperatures revealed field-induced slow magnetization relaxation in these cobalt(II) compounds.
Fields of Study & Subjects
Magnetism in coordination complexes
Metal complexes synthesis and properties
Metal-Organic Frameworks: Synthesis and Applications
Publication details
- Journal / source
- Dalton Transactions
- Publisher
- Royal Society of Chemistry (RSC)
- Volume
- 55
- Issue
- 9
- Pages
- 3840–3852
- Publication date
- 1 January 2026
- Language
- EN