Rhodium porphyrin complexes as catalysts for ammonia borane hydrolytic dehydrogenation

Dalton Transactions 2026 Open access

Read full text
Authors: Manuel Minnucci, Ilaria Barlocco, Laura Prati, Marta Stucchi, Alberto Villa, Gabriele Di Carlo, Francesca Tessore
DOI: 10.1039/d5dt02559a
Cited by: 2
References: 64

Abstract

Here, we report for the first time rhodium porphyrins as single-site catalysts for the hydrolytic dehydrogenation of ammonia borane (AB), overcoming the traditional role of porphyrin-based materials as stabilizing supports for metal nanoparticles.

Fields of Study & Subjects

Hydrogen Storage and Materials Metalloenzymes and iron-sulfur proteins Ammonia Synthesis and Nitrogen Reduction

Publication details

Journal / source
Dalton Transactions
Publisher
Royal Society of Chemistry (RSC)
Volume
55
Issue
5
Pages
2123–2134
Publication date
1 January 2026
Language
EN