Dioxygen-promoted catalytic deformylation of aldehydes via hydrogen atom abstraction by [Fe(TPP)] 2 O

Dalton Transactions 2026 Open access

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Authors: Kai-Chun Hsu, Bhakyaraj Kasi, Tanmoy Pain, Chen‐Hsiung Hung
DOI: 10.1039/d5dt02565f
Cited by: 0
References: 38

Abstract

N) regenerates the active dimer and boosts the yield to 97%. These results provide clear evidence for HAA by a μ-oxo iron(III) porphyrin dimer and underscore its promise for aerobic C-H and C-C bond activations when paired with a suitable base.

Fields of Study & Subjects

Catalytic C–H Functionalization Methods Metal-Catalyzed Oxygenation Mechanisms Oxidative Organic Chemistry Reactions

Publication details

Journal / source
Dalton Transactions
Volume
55
Issue
6
Pages
2465–2470
Publication date
1 January 2026
Language
EN