Spectroscopic and electrochemical studies of tin( iv ) complexes with noninnocent N 2 S 2 and N 2 O 2 ligands based on acenaphthene

Dalton Transactions 2026

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Authors: Liliya D. Labutskaya, Varvara A. Klok, I. V. Krylova, Pavel G. Shangin, Mikhail Evgenievich Minyaev, Evgeny V. Tretyakov, Mikhail A. Syroeshkin, Mikhail Petrovich Egorov, Elena N. Nikolaevskaya
DOI: 10.1039/d5dt02688a
Cited by: 0
References: 48

Abstract

Sn NMR spectroscopy, as well as by X-ray diffraction analysis. The electronic and redox properties of complexes 1-5 were studied using UV spectroscopy and cyclic voltammetry (CV). It was shown that the electrochemical reduction of complexes 1-5 is quasi-reversible. Radical anion derivatives of complexes were described using CV and ESR spectroscopy. The second wave of electrochemical reduction of 1-4 is accompanied by further chemical transformations, while the electroreduction of complex 5 leads to the formation of persistent dianion species.

Fields of Study & Subjects

Synthesis and characterization of novel inorganic/organometallic compounds Organometallic Compounds Synthesis and Characterization Inorganic and Organometallic Chemistry

Publication details

Journal / source
Dalton Transactions
Volume
55
Issue
7
Pages
3073–3086
Publication date
1 January 2026
Language
EN