Electronic structure and magnetic properties of rhenium complexes with an iminoxolene ligand: experimental and computational studies

Dalton Transactions 2026

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Authors: Pavel A. Petrov, Alexey A. Dmitriev, Anastasiia Semikina, Ilia V. Eltsov, Taisiya Sergeevna Sukhikh, А. Н. Лавров, Artem L. Gushchin, Maxim N. Sokolov⧫, Nina P. Gritsan
DOI: 10.1039/d5dt02698a
Cited by: 1
References: 106

Abstract

Novel rhenium complexes with a redox-active ligand exhibit strong metal–ligand π-bonding, a large zero-field splitting, and forbidden transitions in the near-IR region, as confirmed by high-level relativistic ab initio calculations.

Fields of Study & Subjects

Magnetism in coordination complexes Radiopharmaceutical Chemistry and Applications Metal complexes synthesis and properties

Publication details

Journal / source
Dalton Transactions
Publisher
Royal Society of Chemistry (RSC)
Volume
55
Issue
8
Pages
3428–3441
Publication date
1 January 2026
Language
EN