A family of thienyl-bis-salophen Zn( ii ) complexes for enhancing photoconductance in hybrid materials including platinum ultra-small nanoparticles

Read full text
Authors: Mélissa Dumartin, Adeline Pham, Nathalie Saffon‐Merceron, Marine Tassé, Simon Tricard, Claire Kammerer, Jacques Bonvoisin
Cited by: 0
References: 49

Abstract

The design, synthesis and characterization of a series of thienyl-substituted bis-salophen ligands and their related dinuclear Zn(II) complexes are reported, as multifunctional platforms combining the presence of metal centers, multiple free coordinating sites and solubilizing groups. Some of these molecules have been successfully used to elaborate hybrid materials through self-assembly with ultra-small platinum nanoparticles. Interaction of the bis-salophen Zn(II) complexes with the nanoparticles, mediated by the thiophene coordinating moieties, led to a significant enhancement of the photoconductance properties.

Fields of Study & Subjects

Molecular Junctions and Nanostructures Supramolecular Chemistry and Complexes Supramolecular Self-Assembly in Materials

Publication details

Journal / source
Dalton Transactions
Volume
55
Issue
6
Pages
2635–2642
Publication date
1 January 2026
Language
EN