Design and synthesis of Zn( ii )/Cd( ii )-based energetic metal coordination polymers with the bis(tetrazole)methane (H2btm) ligand: a comparative assessment of heat resistance and catalytic effects on the thermal decomposition of ammonium perchlorate
Abstract
and 12.50 GPa, respectively. Both complexes are insensitive to impact (>40 J) and friction (>360 N). The kinetic parameters were determined using the Kissinger and Ozawa methods, and the results are in good agreement with those obtained from the ASTM-E698 method. Additionally, both complexes catalyze the thermal decomposition of ammonium perchlorate (AP). Owing to its high thermal stability, comparable to that of TATB and other H2btm-based complexes, 1 is a promising candidate as a heat-resistant explosive, while both complexes show potential for application in advanced energetic formulations.
Fields of Study & Subjects
Energetic Materials and Combustion
Metal-Organic Frameworks: Synthesis and Applications
Thermal and Kinetic Analysis
Publication details
- Journal / source
- Dalton Transactions
- Publisher
- Royal Society of Chemistry (RSC)
- Volume
- 55
- Issue
- 10
- Pages
- 4204–4214
- Publication date
- 1 January 2026
- Language
- EN