Dynamic reconstructing sulfur vacancies-rich Ni 3 S 2 interfaces for highly selective silane–alcohol dehydrogenation coupling

Dalton Transactions 2026

View at publisher
Authors: Yahui Zhu, Senqun Liu, Wenbo Ye, Jiayao Chen, Shengjun WangWeidong YangJinglan Deng, Rong Zeng, Shunmin Ding, Chao Chen
DOI: 10.1039/d5dt02790j
Cited by: 1
References: 41

Abstract

phase transition induces high-density sulfur vacancies (SVs) in the interfacial region, significantly enhancing substrate adsorption and activation capabilities. Leveraging the synergistic catalysis of this multifunctional interface, the silane-alcohol dehydrogenation coupling reaction achieves 99% conversion and 99% selectivity. This work establishes a novel "multifunctional interface synergistic catalysis" paradigm integrating electronic modulation, structural evolution, and defect engineering, providing theoretical support and practical solutions for economically sustainable organosilicon synthesis technologies.

Fields of Study & Subjects

Catalysis for Biomass Conversion Carbon dioxide utilization in catalysis Catalysis and Hydrodesulfurization Studies

Publication details

Journal / source
Dalton Transactions
Publisher
Royal Society of Chemistry (RSC)
Volume
55
Issue
8
Pages
3509–3520
Publication date
1 January 2026
Language
EN